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And then he did a Heel≯ace Turn right back, but the symbolism is quite strong.
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When paired with anyone Nnoitra (devil) gets this.In fanfics where Ichigo is made to be a sensitive Uke he can be involved in this if he is shipped with Grimmjow, Gin, Hollow Ichigo, or Aizen.Momo being paired with Gin or Aizen exists, too.(It helps that Orihime is the only person Grimmjow ever did a favor for, even if it was for selfish reasons.) GrimmHime is the second most popular Orihime ship behind UlquiHime, with Grimmjow as the Devil and Orihime as the Angel.Orihime/Ulquiorra, especially when symbolism is taken into account (Ulquiorra's released form looks like a fallen angel and his second one is a devil).A Bastard Boyfriend, Depraved Bisexual, Depraved Homosexual, Psycho Lesbian, or a Yandere may be the devil, and The Ingenue, All-Loving Hero, Plucky Girl, or Nice Guy may be the angel. Sometimes a I Have You Now, My Pretty scenario may occur from the devil to the angel. It may overlap with Foe Romance Subtext, Foe Yay Shipping, or Dating Catwoman if the two characters are actual enemies in canon. We all know the appeal of Mind Game Ship, playing another person's mind like it's a game and what not, and this trope can go hand in hand with that one. In Slash Fic or some yaoi, the Uke is often the angel while the Seme is the devil. Generally, a combination of Mind Game Ship and Opposites Attract, with a dash of Draco in Leather Pants, depending on whether the 'ship is canon or not. The main aspect here lies in the fact that the Devil character can do all sorts of things to torment the Angel character, or vice versa, and in the end the two characters will fall in love despite everything or perhaps because of everything (or not if the pairing is one-sided).
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The second character is malicious, rude, possibly perverted, ominously charming, sadistic, etc. Take two characters: one sweet, innocent, kind, loving, naive, maybe even virginal, etc.